title: Easily Vaporizable Ionic Liquids – No Contradiction!
metadata.name: dc.contributor.author
metadata.value: Köckerling Martin, Peppel Tim
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Thiele Philipp, Verevkin Sergey P.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Emel’yanenko Vladimir N., Samarov Artemiy A.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Ruth Wolfgang
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2016-04-08T07:21:34Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2016-04-08T07:21:34Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2015
metadata.lang: -
metadata.name: dc.identifier.issn
metadata.value: 14341948
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/1965
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: It was a big surprise to see crystals of an ionic liquid (IL) forming by sublimation at room temperature. ILs are gen- erally accepted to have negligible vapour pressures at ele- vated temperatures, making their sublimation or distillation very difficult. ILs that sublime easily contain silylimid- azolium-based cations. In order to establish the details of the unusual behaviour of this subclass of ILs, a combined spec- troscopic, X-ray crystallographic, physicochemical and theo-
  retical characterization was performed. The results are com- pared with those of other easily vaporizable compounds, like ammonium chloride and naphthalene. The single-crystal X- ray structure analysis of one of these compounds, N-methyl- N?-dimethyl(phenyl)silylimidazolium chloride (monoclinic, C2/c), clearly shows the existence of isolated ions, demon- strating that the compound is an ionic liquid.
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: en
metadata.lang: en_GB
metadata.name: dc.relation.ispartofseries
metadata.value: European Journal of Inorganic Chemistry;24
metadata.lang: -
metadata.name: dc.subject
metadata.value: Ionic liquids
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Silylimidazoles
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Boiling point
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Solid-state structures
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Thermochemistry
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Sublimation
metadata.lang: en_GB
metadata.name: dc.title
metadata.value: Easily Vaporizable Ionic Liquids – No Contradiction!
metadata.lang: en_GB
metadata.name: dc.type
metadata.value: Article
metadata.lang: en_GB
resources.filename: Köckerling et al. - 2015 - Easily Vaporizable Ionic Liquids - No Contradiction!.pdf
resources.url: https://dspace.spbu.ru/bitstream/11701/1965/1/K%c3%b6ckerling%20et%20al.%20-%202015%20-%20Easily%20Vaporizable%20Ionic%20Liquids%20-%20No%20Contradiction%21.pdf
resources.format: Adobe PDF
resources.size: 5,06 MB