title: Exchange of aryl groups in Friedel — Crafts alkylation of arenes in superacid by 2-halogeno- 2-trifluoromethylstyrenes. Mechanism and ways of suppression
metadata.name: dc.contributor.author
metadata.value: Sandzhieva, Maria A.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Muzalevskiy, Vasiliy M.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Nenajdenko, Valentine G.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Vasilyev, Aleksander V.
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2018-04-26T09:05:31Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2018-04-26T09:05:31Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2018-03
metadata.lang: -
metadata.name: dc.identifier.citation
metadata.value: SandzhievaM. A., Muzalevskiy V.M., Nenajdenko V. G., Vasilyev A. V. Exchange of aryl groups in Friedel — Crafts alkylation of arenes in superacid by 2-halogeno- 2-trifluoromethylstyrenes. Mechanism and ways of suppression. Vestnik SPbSU. Physics and Chemistry. 2018. Vol. 5 (63), iss. 1. P. 50–58.
metadata.lang: en_GB
metadata.name: dc.identifier.other
metadata.value: 10.21638/11701/spbu04.2018.106
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/9490
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: The protonation of 2-halogeno-2-trifluoromethylstyrenes in superacids leads to formation of benzyl
  carbocations that are capable to take part in Friedel — Crafts reaction with arenes to afford 1,1-
  diaryl-2-halo-3,3,3-trifluoropropanes. The reaction with strong π-nucleophiles (xylenes, anisole or
  veratrole) can be complicated by exchange of aryl groups. The mechanism and ways of suppression
  of this additional process were proposed.
metadata.lang: en_GB
metadata.name: dc.description.sponsorship
metadata.value: Данное исследование выполнено при финансовой поддержке Фонда содействия инновациям
  (№11304 ГУ/2016 от 14,04,2017).
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: ru
metadata.lang: en_GB
metadata.name: dc.publisher
metadata.value: St Petersburg State University
metadata.lang: en_GB
metadata.name: dc.relation.ispartofseries
metadata.value: Vestnik of St Petersburg University. Physics and Chemistry;Volume 5(63); Issue 1
metadata.lang: -
metadata.name: dc.subject
metadata.value: superelectrophilic activation
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: trifluoromethylstyrenes
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: carbocations
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: superacid
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Friedel — Crafts reaction
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: hydroarylation of double bond
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: exhange of aryl groups
metadata.lang: en_GB
metadata.name: dc.title
metadata.value: Exchange of aryl groups in Friedel — Crafts alkylation of arenes in superacid by 2-halogeno- 2-trifluoromethylstyrenes. Mechanism and ways of suppression
metadata.lang: en_GB
metadata.name: dc.type
metadata.value: Article
metadata.lang: en_GB
resources.filename: 06-Sandzhieva.pdf
resources.url: https://dspace.spbu.ru/bitstream/11701/9490/1/06-Sandzhieva.pdf
resources.format: Adobe PDF
resources.size: 384,68 kB