title: Oxocentered Cu(II) lead selenite honeycomb lattices hosting Cu(I)Cl2 groups obtained by chemical vapor transport reactions
metadata.name: dc.contributor.author
metadata.value: Kovrugin, Vadim M
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Colmont, Marie
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Siidra, Oleg I
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Mentré, Olivier
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Al-Shuray, Alexander
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Gurzhiy, Vladislav V
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Krivovichev, Sergey V
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2016-05-06T12:17:22Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2016-05-06T12:17:22Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2015-06-11
metadata.lang: -
metadata.name: dc.identifier
metadata.value: 10.1039/c5cc01426c
metadata.lang: -
metadata.name: dc.identifier.issn
metadata.value: 10.1039/c5cc01426c
metadata.lang: -
metadata.name: dc.identifier.issn
metadata.value: 1359-7345
metadata.lang: -
metadata.name: dc.identifier.other
metadata.value: 10.1039/c5cc01426c
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/2240
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: Chemical vapor transport (CVT) reactions were used to prepare three modular mixed-valent Cu(I)-Cu(II) compounds, (Pb2Cu(2+)9O4)(SeO3)4(Cu(+)Cl(2))Cl5 (1), (PbCu(2+)5O2)(SeO3)2(Cu(+)Cl2)Cl3 (2), and (Pb(x)Cu(2+)(6-x)O2)(SeO3)2(Cu(+)Cl2)K(1-x)Cl(4-x) (x = 0.20) (3). In their crystal structures chains of anion-centered (OCu(2+)4) and (OCu(2+)3Pb) tetrahedra form honeycomb-like double layers with cavities occupied by linear [Cu(+)Cl2](-) groups.
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: en
metadata.lang: en_GB
metadata.name: dc.publisher
metadata.value: Royal Society of Chemistry
metadata.lang: en_GB
metadata.name: dc.relation.ispartofseries
metadata.value: Chemical Communications;V. 51. Issue 46
metadata.lang: -
metadata.name: dc.title
metadata.value: Oxocentered Cu(II) lead selenite honeycomb lattices hosting Cu(I)Cl2 groups obtained by chemical vapor transport reactions
metadata.lang: en_GB
metadata.name: dc.type
metadata.value: Article
metadata.lang: en_GB
resources.filename: 2015_Kovrugin_Chem Comm.pdf
resources.url: https://dspace.spbu.ru/bitstream/11701/2240/1/2015_Kovrugin_Chem%20Comm.pdf
resources.format: Adobe PDF
resources.size: 2,4 MB