title: Trifluoromethylated allyl alcohols: acid-promoted reactions with arenes and unusual ‘dimerization’
metadata.name: dc.contributor.author
metadata.value: Kazakova, Anna N.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Iakovenko, Roman O.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Muzalevskiy, Vasiliy M.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Boyarskaya, Irina A.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Avdontceva, Margarita S.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Starova, Galina L.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Vasilyev, Aleksander V.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Nenajdenko, Valentine G.
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2016-04-10T19:08:53Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2016-04-10T19:08:53Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2014
metadata.lang: -
metadata.name: dc.identifier.issn
metadata.value: 0040-4039
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/2039
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: An unusual ‘dimerization’ of CF3-allyl alcohols [ArCH@CHCH(OH)CF3] under the action of anhydrous FeCl3 was found to give fluorinated indanes in 62–90% yields via the formation of intermediate allyl cations. Reactions of CF3-allyl alcohols with arenes (Ar0H) led to CF3-alkenes in 48–75% yields. The mechanisms of the transformations are discussed.
metadata.lang: en_GB
metadata.name: dc.description.sponsorship
metadata.value: This work was supported by SPbSU (Grants no. 12.50.1558.2013, and no. 12.38.195.2014)
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: en
metadata.lang: en_GB
metadata.name: dc.publisher
metadata.value: Elsevier
metadata.lang: en_GB
metadata.name: dc.relation.ispartofseries
metadata.value: Tetrahedron Letters;55, pp. 6851-6855
metadata.lang: -
metadata.name: dc.subject
metadata.value: CF3-allyl alcohols
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: CF3-alkenes
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Iron trichloride
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Fluorinated indanes
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: CF3-allyl carbocations
metadata.lang: en_GB
metadata.name: dc.title
metadata.value: Trifluoromethylated allyl alcohols: acid-promoted reactions with arenes and unusual ‘dimerization’
metadata.lang: en_GB
metadata.name: dc.type
metadata.value: Article
metadata.lang: en_GB
resources.filename: T_AllylCF3paperBM[5].doc
resources.url: https://dspace.spbu.ru/bitstream/11701/2039/1/T_AllylCF3paperBM%5b5%5d.doc
resources.format: Microsoft Word
resources.size: 2,4 MB