title: Uranyl Sulfate Nanotubules Templated by N-phenylglycine
metadata.name: dc.contributor.author
metadata.value: Siidra, Oleg I
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Nazarchuk, Evgeny V
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Charkin, Dmitry O
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Chukanov, Nikita V
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Depmeier, Wulf
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Bocharov, Sergey N
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Sharikov, Mikhail I
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2018-07-01T08:25:54Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2018-07-01T08:25:54Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2018-04-03
metadata.lang: -
metadata.name: dc.identifier
metadata.value: 10.3390/nano8040216
metadata.lang: -
metadata.name: dc.identifier.issn
metadata.value: 10.3390/nano8040216
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/10355
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH⁺)₇[(UO₂)₆(SO₄)10](H₂O)3.5 (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO₂)₆(SO₄)10]8- nanotubules templated by protonated N-phenylglycine (C₆H₅NH₂CH₂COOH)⁺. Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO₄ tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π-π interaction with their side chains extending into the gaps between the nanotubules.
metadata.lang: en_GB
metadata.name: dc.description.sponsorship
metadata.value: This work was financially supported by the Russian Science Foundation through the grant
  16-17-10085. Technical support by the SPbSU X-ray Diffraction, Thermal Analysis and Calorimetry, Microscopy
  and Microanalysis Resource Centers is gratefully acknowledged.
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: en
metadata.lang: en_GB
metadata.name: dc.publisher
metadata.value: MDPI
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: nanostructured materials
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: nanotubes
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: actinide materials
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: organically templated compounds
metadata.lang: en_GB
metadata.name: dc.title
metadata.value: Uranyl Sulfate Nanotubules Templated by N-phenylglycine
metadata.lang: en_GB
resources.filename: nanomaterials_1.compressed.pdf
resources.url: https://dspace.spbu.ru/bitstream/11701/10355/1/nanomaterials_1.compressed.pdf
resources.format: Adobe PDF
resources.description: Main article
resources.size: 647,21 kB