title: Metal-involving generation of aminoheterocycles from N-substituted cyanamides: toward sustainable chemistry (a minireview)
metadata.name: dc.contributor.author
metadata.value: Bolotin, Dmitrii S.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Rassadin, Valentin A.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Bokach, Nadezhda A.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Kukushkin, Vadim Yu.
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2016-04-15T15:48:57Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2016-04-15T15:48:57Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2016
metadata.lang: -
metadata.name: dc.identifier.issn
metadata.value: 0020-1693
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/2101
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: This review is focused on progress in the area of metal-involving reactions of cyanamides leading to aminosubstituted heterocycles. The consideration covers metal-mediated cyanamide–amidoxime coupling giving 5-aminosubstituted 1,2,4-oxadiazoles and cycloaddition of nitrones or azides to cyanamide species furnishing 5-aminosubstituted 2,3-dihydro-1,2,4-oxadiazoles and 5-aminotetrazoles, respectively. Gold-catalyzed heterocyclization of cyanamides and acetylenes providing 2-aminooxazole systems is also considered. All these reaction schemes are discussed from viewpoints of sustainable processes with particular focus on how application of metal-involving reactions to organic transformations of cyanamides provides milder reaction conditions, increase yields of target products, and reduce number of reactions steps thus making the chemistry of cyanamides more environmentally benign.
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: en
metadata.lang: en_GB
metadata.name: dc.publisher
metadata.value: Elsevier
metadata.lang: en_GB
metadata.name: dc.relation.ispartofseries
metadata.value: Inorganica Chimica Acta;accepted
metadata.lang: -
metadata.name: dc.subject
metadata.value: Cyanamides
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: metal-involving reactions
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: N-substituted heterocycles
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: 1,3-dipolar cycloaddition
metadata.lang: en_GB
metadata.name: dc.title
metadata.value: Metal-involving generation of aminoheterocycles from N-substituted cyanamides: toward sustainable chemistry (a minireview)
metadata.lang: en_GB
metadata.name: dc.type
metadata.value: Article
metadata.lang: en_GB
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resources.url: https://dspace.spbu.ru/bitstream/11701/2101/1/GA_final_version.jpg
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