title: Cu(I)−NHC-Catalyzed (2 + 3)-Annulation of Tetramic Acids with 2H‑Azirines: Stereoselective Synthesis of Functionalized Hexahydropyrrolo[3,4‑b]pyrroles
metadata.name: dc.contributor.author
metadata.value: Rostovskii, Nikolai V.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Sakharov, Pavel A.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Novikov, Mikhail S.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Khlebnikov, Alexander F.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Starova, Galina L.
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2016-04-07T20:31:05Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2016-04-07T20:31:05Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2015-09
metadata.lang: -
metadata.name: dc.identifier.citation
metadata.value: Org. Lett. 2015, 17, 4148−4151
metadata.lang: en_GB
metadata.name: dc.identifier.issn
metadata.value: 1523-7060
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/1957
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: A stereoselective and high-yield synthesis of hexahydropyrrolo[3,4-b]pyrroles from tetramic acids and 2H-azirines under Cu(I)−NHC catalysis is developed. An unusual N−C2 azirine bond cleavage, initiated by a copper enolate, was rationalized in terms of a free radical reaction mechanism.
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: en
metadata.lang: en_GB
metadata.name: dc.publisher
metadata.value: American Chemical Society
metadata.lang: en_GB
metadata.name: dc.relation.ispartofseries
metadata.value: Organic Letters;Vol. 17
metadata.lang: -
metadata.name: dc.subject
metadata.value: Tetramic Acids
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: copper
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Azirines
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: pyrrole
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: organic synthesis
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: catalysis
metadata.lang: en_GB
metadata.name: dc.title
metadata.value: Cu(I)−NHC-Catalyzed (2 + 3)-Annulation of Tetramic Acids with 2H‑Azirines: Stereoselective Synthesis of Functionalized Hexahydropyrrolo[3,4‑b]pyrroles
metadata.lang: en_GB
metadata.name: dc.type
metadata.value: Article
metadata.lang: en_GB
resources.filename: grafical abstract.png
resources.url: https://dspace.spbu.ru/bitstream/11701/1957/1/grafical%20abstract.png
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