title: Synthesis and structure of dinitrosyl iron complexes with secondary thiolate bridging ligands [Fe2(μ-SCHR2)2(NO)4], R = Me, Ph
metadata.name: dc.contributor.author
metadata.value: Davidovich, Pavel B.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Gurzhiy, Vladislav V.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Sanina, N.A.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Shchukarev, A.V.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Garabadzhiu, A.V.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Belyaev, A.N.
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2016-05-06T11:50:47Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2016-05-06T11:50:47Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2015-04
metadata.lang: -
metadata.name: dc.identifier.citation
metadata.value: doi:10.1016/j.poly.2015.02.009
metadata.lang: en_GB
metadata.name: dc.identifier.issn
metadata.value: 0277-5387
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/2238
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: New dinitrosyl iron complexes of binuclear structure [Fe2(μ-SCHMe2)2(NO)4] and [Fe2(μ-SCHPh2)2(NO)4] were first synthesized employing new method from Fe(CO)5, corresponding thiol, and EtONO. Complexes structures were determined by XRD technique. DFT calculations were performed to probe the cis-conformer structures in gas and solution phases. NO donor ability of the complex with isopropyl thiolate ligand was studied.
metadata.lang: en_GB
metadata.name: dc.description.sponsorship
metadata.value: The work has been supported by the Ministry of Education and Science of the Russian Federation (State Contract 14.B25.310013) and the Program of the Presidium of RAS “Fundamental sciences for medicine”. XRD study has been prepared at the X-ray Diffraction Centre of Saint-Petersburg State University. NMR studies were performed by S. Smirnov at the Centre for Magnetic Resonance of Saint-Petersburg State University
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: en
metadata.lang: en_GB
metadata.name: dc.publisher
metadata.value: Elsevier
metadata.lang: en_GB
metadata.name: dc.relation.ispartofseries
metadata.value: Polyhedron;V. 90.
metadata.lang: -
metadata.name: dc.subject
metadata.value: Crystal structure
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Thiolate ligands
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Dinitrosyl iron complex
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Nitric oxide donor
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: DFT calculations
metadata.lang: en_GB
metadata.name: dc.title
metadata.value: Synthesis and structure of dinitrosyl iron complexes with secondary thiolate bridging ligands [Fe2(μ-SCHR2)2(NO)4], R = Me, Ph
metadata.lang: en_GB
metadata.name: dc.type
metadata.value: Article
metadata.lang: en_GB
resources.filename: 2015_Davidovich_Polyhedron_Fe.pdf
resources.url: https://dspace.spbu.ru/bitstream/11701/2238/1/2015_Davidovich_Polyhedron_Fe.pdf
resources.format: Adobe PDF
resources.size: 651,31 kB