title: Hybrid One-Dimensional 15-Crown-5-ether-uranyl-selenate Polymers in [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)]: Synthesis and Characterization
metadata.name: dc.contributor.author
metadata.value: Gurzhiy, Vladislav V.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Tyumentseva, Olga S.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Krivovichev, Sergey V.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Tananaev, Ivan G.
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2016-05-06T12:40:31Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2016-05-06T12:40:31Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2015-05
metadata.lang: -
metadata.name: dc.identifier.issn
metadata.value: 1521-3749
metadata.lang: -
metadata.name: dc.identifier.other
metadata.value: 10.1002/zaac.201500208
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/2242
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: The hybrid organic-inorganic uranyl selenate, [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)] (I), was prepared by isothermal evaporation from aqueous solutions. The crystal structure of I [orthorhombic, Pnma, a = 15.386(3), b = 10.771(2), c = 13.239(3) Å, V = 2194.0(7) Å3, Z = 4, R1 = 0.042] is based upon complex 15-crown-5-ether-uranyl-selenate polymeric units consisting of uranyl selenate chains decorated by [K@(15-crown-5)]+ complexes via strong ionic K+–O bonds. The 1D hybrid units are packed in a parquetted-like fashion and connected to each other by hydrogen bonds and residual van der Waals interactions.
metadata.lang: en_GB
metadata.name: dc.description.sponsorship
metadata.value: This work was supported by St. Petersburg State University (grant 3.38.136.2014) and President of Russian Federation grant for young scientists (no. MK-1737.2014.5 to V. V. G.). The XRD studies have been performed at the X-ray Diffraction Centre of St. Petersburg State University.
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: en
metadata.lang: en_GB
metadata.name: dc.publisher
metadata.value: Wiley
metadata.lang: en_GB
metadata.name: dc.relation.ispartofseries
metadata.value: Zeitschrift für anorganische und allgemeine Chemie;V. 641. Issue 6
metadata.lang: -
metadata.name: dc.subject
metadata.value: Uranyl selenate
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Crown ether
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Potassium
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Topology
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Crystal structure
metadata.lang: en_GB
metadata.name: dc.title
metadata.value: Hybrid One-Dimensional 15-Crown-5-ether-uranyl-selenate Polymers in [K@(C10H20O5)][(UO2)(SeO4)(HSeO4)(H2O)]: Synthesis and Characterization
metadata.lang: en_GB
metadata.name: dc.type
metadata.value: Article
metadata.lang: en_GB
resources.filename: 2015_ZAAC_KUSeCr.pdf
resources.url: https://dspace.spbu.ru/bitstream/11701/2242/1/2015_ZAAC_KUSeCr.pdf
resources.format: Adobe PDF
resources.size: 442,79 kB