title: Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds
metadata.name: dc.contributor.author
metadata.value: Gurzhiy, Vladislav V.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Al-Shuray, Alexander A.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Britvin, Sergey N.
metadata.lang: -
metadata.name: dc.contributor.author
metadata.value: Krivovichev, Sergey V.
metadata.lang: -
metadata.name: dc.date.accessioned
metadata.value: 2016-05-06T12:48:38Z
metadata.lang: -
metadata.name: dc.date.available
metadata.value: 2016-05-06T12:48:38Z
metadata.lang: -
metadata.name: dc.date.issued
metadata.value: 2015-11
metadata.lang: -
metadata.name: dc.identifier.issn
metadata.value: 1099-0682
metadata.lang: -
metadata.name: dc.identifier.other
metadata.value: 10.1002/ejic.201500927
metadata.lang: -
metadata.name: dc.identifier.uri
metadata.value: http://hdl.handle.net/11701/2243
metadata.lang: -
metadata.name: dc.description.abstract
metadata.value: Cu3(SeO4)2(SeO3OH)2(H2O)16 (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral–tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)4O2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn–Teller distortion of the octahedral coordination geometry of Cu2+.
metadata.lang: en_GB
metadata.name: dc.description.sponsorship
metadata.value: This work was supported by the Russian Science Foundation (grant 14-17-00071). X-ray diffraction studies have been carried out at the XRD Centre of Saint-Petersburg State University.
metadata.lang: en_GB
metadata.name: dc.language.iso
metadata.value: en
metadata.lang: en_GB
metadata.name: dc.publisher
metadata.value: Wiley
metadata.lang: en_GB
metadata.name: dc.relation.ispartofseries
metadata.value: European Journal of Inorganic Chemistry;V. 2015. Issue 32
metadata.lang: -
metadata.name: dc.subject
metadata.value: Copper
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Chalcogens
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Hept­amers
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Jahn–Teller distortion
metadata.lang: en_GB
metadata.name: dc.subject
metadata.value: Structure elucidation
metadata.lang: en_GB
metadata.name: dc.title
metadata.value: Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds
metadata.lang: en_GB
metadata.name: dc.type
metadata.value: Article
metadata.lang: en_GB
resources.filename: 2015_EurJInorgChem_Cu Se heptamer.pdf
resources.url: https://dspace.spbu.ru/bitstream/11701/2243/1/2015_EurJInorgChem_Cu%20Se%20heptamer.pdf
resources.format: Adobe PDF
resources.size: 1,74 MB